GIEC OpenIR  > 中国科学院广州能源研究所
Promoting Hydrolytic Hydrogenation of Cellulose to Sugar Alcohols by Mixed Ball Milling of Cellulose and Solid Acid Catalyst
Liao, Yuhe1,2; Liu, Qiying1; Wang, Tiejun1; Long, Jinxing1; Zhang, Qi1; Ma, Longlong1; Liu, Yong1,2; Li, Yuping1
2014-09-01
Source PublicationENERGY & FUELS
Volume28Issue:9Pages:5778-5784
AbstractEnhancing the contact or interaction between cellulose and solid catalyst is a significant aspect in its efficient catalytic conversion. Herein, mixed ball milling of cellulose and solid catalyst was presented to achieve this goal, and the promotion effect was measured by hydrolytic hydrogenation of cellulose to sugar alcohols (the platform compounds for biogasoline) with solid acid and commercial 5 wt 96 Ru/C in water. The effects of ball-milling modes, time, and reaction parameters were studied. The properties of cellulose and solid add catalyst before and after treatment were also analyzed. The yield of sugar alcohols reached 90.3% at 463 K with amorphous zirconium phosphate and Ru/C (mixed ball-milling time of 2 h). This high yield of sugar alcohols achieved in the mixed ball-milling time of 2 h was 12 times faster than that by the single ball milling of 24 h under the same reaction conditions. It is ascribed to the enhanced contact between cellulose and catalyst, resulting in promoting cellulose depolymerization. The high concentration of sugar alcohols up to 67 mg/mL was obtained by augmenting the mass ratio of cellulose/catalyst.
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/ef500717p
WOS Subject ExtendedEnergy & Fuels ; Engineering
WOS KeywordLIGNOCELLULOSIC BIOMASS ; ZIRCONIUM-PHOSPHATE ; CONVERSION ; WATER ; DEPOLYMERIZATION ; HYDROCARBONS ; BIOREFINERY ; GLUCOSE ; ENZYMES ; CARBON
Indexed BySCI
Language英语
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000342118200023
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10654
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Liao, Yuhe,Liu, Qiying,Wang, Tiejun,et al. Promoting Hydrolytic Hydrogenation of Cellulose to Sugar Alcohols by Mixed Ball Milling of Cellulose and Solid Acid Catalyst[J]. ENERGY & FUELS,2014,28(9):5778-5784.
APA Liao, Yuhe.,Liu, Qiying.,Wang, Tiejun.,Long, Jinxing.,Zhang, Qi.,...&Li, Yuping.(2014).Promoting Hydrolytic Hydrogenation of Cellulose to Sugar Alcohols by Mixed Ball Milling of Cellulose and Solid Acid Catalyst.ENERGY & FUELS,28(9),5778-5784.
MLA Liao, Yuhe,et al."Promoting Hydrolytic Hydrogenation of Cellulose to Sugar Alcohols by Mixed Ball Milling of Cellulose and Solid Acid Catalyst".ENERGY & FUELS 28.9(2014):5778-5784.
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