Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts

doi:10.7503/cjcu20140464

GIEC OpenIR > 中国科学院广州能源研究所

	Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts
	Li Yanbin 1,2; Xu Ying 2,3; Ma Longlong 1,2,3; Zhang Qi 2,3; Wang Tiejun 2,3; Chen Guanyi 1; Zhang Limin 2
	2014-12-10
发表期刊	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号	35 期号:12 页码:2654-2661
摘要	In situ hydrogenation was studied by means of Ni loading, temperature, initial pressure, and reaction time over Ni/CMK-3 catalysts. The catalysts were characterized by X-ray diffraction(XRD), H-2 temperature programmed reduction(H-2-TPR) and N-2 adsorption-desorption isotherms. The results revealed that the optimal conditions were confirmed as follow: Ni loading of 20% (mass fraction), reaction temperature of 230 degrees C, initial pressure of 0. 1 MPa, reaction time of 9 h for in situ hydrogenation. The maximum conversion of o-cresol in optimal condition was determined as 47. 56%. Compared with the effect of hydrogen donor solvents, formic acid was the best of four kinds of solvents. The comparsion of cresol isomers, recyclability of Ni/CMK-3 were also discussed.
文章类型	Article
关键词	In Situ Hydrogenation O-cresol Nickel-based Cmk-3 Catalyst
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.7503/cjcu20140464
研究领域[WOS]	Chemistry
关键词[WOS]	OIL MODEL COMPOUNDS ; BIO-OIL ; PLATINUM CATALYSTS ; GENERATED HYDROGEN ; MESOPOROUS CARBONS ; PYROLYSIS OIL ; HYDRODEOXYGENATION ; PHENOL ; PERFORMANCE ; COMPOUND
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000347669400025
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10643
专题	中国科学院广州能源研究所
作者单位	1.Tianjin Univ, State Key Lab Int Combust Engine, Fac Environm Sci & Engn, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Li Yanbin,Xu Ying,Ma Longlong,et al. Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2014,35(12):2654-2661.
APA	Li Yanbin.,Xu Ying.,Ma Longlong.,Zhang Qi.,Wang Tiejun.,...&Zhang Limin.(2014).Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,35(12),2654-2661.
MLA	Li Yanbin,et al."Research on in situ Hydrogenation of o-Cresol over Ni/CMK-3 Catalysts".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 35.12(2014):2654-2661.