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Amine-functionalized metal-organic frameworks for the transesterification of triglycerides
Chen, Jinzhu1; Liu, Ruliang1,3; Gao, Hui1,2; Chen, Limin2; Ye, Daiqi2
2014
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
Volume2Issue:20Pages:7205-7213
AbstractFor the application of functionalized metal-organic frameworks (MOFs) as a solid base, amine-functionalized MOF materials are achieved by (i) dative modification of unsaturated metal sites located at the secondary building units of MOFs with diamine, and (ii) covalent modification of the amine-tagged organic linkers within the MOF by alkylation with 2-dimethylaminoethyl chloride. The resulting amine-functionalized MOFs exhibit excellent results in the liquid phase transesterification of triglycerides and methanol, with the triglyceride conversions exceeding 99%, which are important model reactions for the production of biodiesel. The relationship between the catalytic activity towards transesterification and the basicity of amine-functionalized MOFs reveals a linear correspondence in terms of turnover frequency and basic site density. The basicity of the MOFs and reaction parameters are shown to significantly affect the catalytic performance. Kinetics studies reveal that the reaction follows first-order kinetics with the calculated activation energy of 48.2 kJ mol(-1). This research opens up new perspectives on the postsynthetic modification of MOFs and more generally on the rational design of MOF-derived solid base catalysts.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1039/c4ta00253a
WOS Subject ExtendedChemistry ; Energy & Fuels ; Materials Science
WOS KeywordADSORPTION PROPERTIES ; HETEROGENEOUS CATALYST ; COORDINATION POLYMERS ; HYDROGEN ADSORPTION ; BIODIESEL SYNTHESIS ; RATIONAL DESIGN ; CO2 ADSORPTION ; FATTY-ACIDS ; MOFS ; ETHYLENEDIAMINE
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000334998400012
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10608
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.S China Univ Technol, Coll Environm & Energy, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Chen, Jinzhu,Liu, Ruliang,Gao, Hui,et al. Amine-functionalized metal-organic frameworks for the transesterification of triglycerides[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(20):7205-7213.
APA Chen, Jinzhu,Liu, Ruliang,Gao, Hui,Chen, Limin,&Ye, Daiqi.(2014).Amine-functionalized metal-organic frameworks for the transesterification of triglycerides.JOURNAL OF MATERIALS CHEMISTRY A,2(20),7205-7213.
MLA Chen, Jinzhu,et al."Amine-functionalized metal-organic frameworks for the transesterification of triglycerides".JOURNAL OF MATERIALS CHEMISTRY A 2.20(2014):7205-7213.
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