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Phase Equilibrium Data of the Double Tetrabutylammonium Chloride Plus Carbon Dioxide or Nitrogen Semiclathrate Hydrate
Shi, Ling-Li1,2; Liang, De-Qing1; Wu, Neng-You1
2014-07-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号59期号:7页码:2320-2323
摘要In this paper, phase equilibrium data of the double tetrabutylammonium chloride (TBACl: C16H36ClN) semidathrate hydrate with a guest gas (CO2 or N-2) at four different TBACl concentrations (0.06, 0.15, 0.34, and 0.44 mass fraction) were experimentally measured by employing an isochoric pressure-search method in the temperature range of (282.9 to 293.2) K and at pressures up to 13.57 MPa, respectively. The results demonstrated that double TBACl + CO2 (or N-2) semidathrate hydrates had an obvious advantage in thermal stability compared to pure CO2 (or N-2) hydrates. And the strongest stabilization effect was observed with the application of TBACl at 0.34 mass fraction, corresponding to TBACl center dot 30H(2)O. In addition, the results were compared with the corresponding data reported in open literature. The comparisons showed that some literature data seemed to be not reliable.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1021/je500445w
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]N-BUTYLAMMONIUM BROMIDE ; DISSOCIATION CONDITIONS ; AMMONIUM-CHLORIDE ; WATER ; CO2 ; HYDROGEN ; METHANE ; MIXTURES ; BINARY ; SYSTEM
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000338981000025
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10602
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Shi, Ling-Li,Liang, De-Qing,Wu, Neng-You. Phase Equilibrium Data of the Double Tetrabutylammonium Chloride Plus Carbon Dioxide or Nitrogen Semiclathrate Hydrate[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2014,59(7):2320-2323.
APA Shi, Ling-Li,Liang, De-Qing,&Wu, Neng-You.(2014).Phase Equilibrium Data of the Double Tetrabutylammonium Chloride Plus Carbon Dioxide or Nitrogen Semiclathrate Hydrate.JOURNAL OF CHEMICAL AND ENGINEERING DATA,59(7),2320-2323.
MLA Shi, Ling-Li,et al."Phase Equilibrium Data of the Double Tetrabutylammonium Chloride Plus Carbon Dioxide or Nitrogen Semiclathrate Hydrate".JOURNAL OF CHEMICAL AND ENGINEERING DATA 59.7(2014):2320-2323.
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