Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax

doi:10.1080/15567036.2011.631974

GIEC OpenIR > 中国科学院广州能源研究所

	Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax
	Zhang, H. R.1; Ding, F.1,2; Luo, C. R.1; Chen, X. D.1
	2015
发表期刊	ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
卷号	37 期号:15 页码:1612-1619
摘要	The pyrolysis of polypropylene to polypropylene wax in a 1-L autoclave has been studied at low temperature. A four-lump kinetics model of pyrolysis of polypropylene to polypropylene wax, gaseous and liquid products is performed, and the kinetic parameters of the conversion of polypropylene into different products are determined. The total activation energy for the conversion of polypropylene was estimated to be 214 kJ mol(-1). The polypropylene wax obtained had a drop melting point of 121-150 degrees C, and the weight average molecular was 7,419 g/mol. Fourier transform infrared analysis of the polypropylene wax showed that it is less branched and that its olefinic content is higher than that of commercial wax.
文章类型	Article
关键词	Cracking Kinetics Lumping Polypropylene Polyethylene Wax
WOS标题词	Science & Technology ; Technology ; Life Sciences & Biomedicine
DOI	10.1080/15567036.2011.631974
研究领域[WOS]	Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
关键词[WOS]	CRUDE OILS ; PYROLYSIS ; THERMOMICROSCOPY ; POLYETHYLENE ; POLYSTYRENE ; POLYOLEFINS ; REACTOR ; WASTE
收录类别	SCI
语种	英语
WOS类目	Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS记录号	WOS:000358301400003
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10534
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Zhang, H. R.,Ding, F.,Luo, C. R.,et al. Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax[J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,2015,37(15):1612-1619.
APA	Zhang, H. R.,Ding, F.,Luo, C. R.,&Chen, X. D..(2015).Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax.ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,37(15),1612-1619.
MLA	Zhang, H. R.,et al."Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax".ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS 37.15(2015):1612-1619.