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Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax
Zhang, H. R.1; Ding, F.1,2; Luo, C. R.1; Chen, X. D.1
2015
发表期刊ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
卷号37期号:15页码:1612-1619
摘要The pyrolysis of polypropylene to polypropylene wax in a 1-L autoclave has been studied at low temperature. A four-lump kinetics model of pyrolysis of polypropylene to polypropylene wax, gaseous and liquid products is performed, and the kinetic parameters of the conversion of polypropylene into different products are determined. The total activation energy for the conversion of polypropylene was estimated to be 214 kJ mol(-1). The polypropylene wax obtained had a drop melting point of 121-150 degrees C, and the weight average molecular was 7,419 g/mol. Fourier transform infrared analysis of the polypropylene wax showed that it is less branched and that its olefinic content is higher than that of commercial wax.
文章类型Article
关键词Cracking Kinetics Lumping Polypropylene Polyethylene Wax
WOS标题词Science & Technology ; Technology ; Life Sciences & Biomedicine
DOI10.1080/15567036.2011.631974
研究领域[WOS]Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
关键词[WOS]CRUDE OILS ; PYROLYSIS ; THERMOMICROSCOPY ; POLYETHYLENE ; POLYSTYRENE ; POLYOLEFINS ; REACTOR ; WASTE
收录类别SCI
语种英语
WOS类目Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS记录号WOS:000358301400003
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10534
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
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Zhang, H. R.,Ding, F.,Luo, C. R.,et al. Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax[J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,2015,37(15):1612-1619.
APA Zhang, H. R.,Ding, F.,Luo, C. R.,&Chen, X. D..(2015).Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax.ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS,37(15),1612-1619.
MLA Zhang, H. R.,et al."Kinetics of the Low Temperature Conversion of Polypropylene to Polypropylene Wax".ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS 37.15(2015):1612-1619.
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