GIEC OpenIR  > 中国科学院广州能源研究所
Efficient synthesis of biofuel precursor with long carbon chains from fructose
Tan, Jin1,2; Liu, Qiying1; Cai, Chiliu1; Qiu, Songbai1; Wang, Tiejun1; Zhang, Qi1; Ma, Longlong1,2; Chen, Guanyi2
2015
Source PublicationRSC ADVANCES
Volume5Issue:72Pages:58784-58789
AbstractLong carbon biofuel precursors were efficiently synthesized via Aldol condensation of furans (furfural, 5-ethoxymethylfurfural, 5-hydroxymethylfural) and their derivatives (levulinic acid, ethyl levulinate) which were co-produced by fructose transformation in ethanol using acidic metal salt catalysts. High yields of furans and their derivatives were obtained and their mole ratios were adjusted. The effects of reaction time, temperature and water content on the mole ratios of furans and their derivatives were investigated in detail. The condensation reaction was conducted directly when the mole ratio of furans and their derivatives was located in the range of 1 to 2. The results showed that a total mole yield of furans and their derivatives as high as 91.6% could be obtained after fructose alcoholysis at 413 K for 2.0 h using Fe-2(SO4)(3) as a catalyst. After that, Aldol condensations of the produced furans and their derivatives with mole ratios of 1.9 and 1.1 were directly conducted using NaOH as the catalyst and 91.2% and 89.1% yields of precursors were gained, respectively. This technical route indicates a simple and feasible method to produce renewable long carbon biofuel from biomass.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c5ra07448g
WOS Subject ExtendedChemistry
WOS KeywordPLATFORM MOLECULES ; CONVERSION ; BIOMASS ; CHEMICALS ; FUELS ; ACID ; CATALYSTS ; LIGNOCELLULOSE ; CONDENSATION ; ALKANES
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000357798400080
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10526
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300072, Peoples R China
Recommended Citation
GB/T 7714
Tan, Jin,Liu, Qiying,Cai, Chiliu,et al. Efficient synthesis of biofuel precursor with long carbon chains from fructose[J]. RSC ADVANCES,2015,5(72):58784-58789.
APA Tan, Jin.,Liu, Qiying.,Cai, Chiliu.,Qiu, Songbai.,Wang, Tiejun.,...&Chen, Guanyi.(2015).Efficient synthesis of biofuel precursor with long carbon chains from fructose.RSC ADVANCES,5(72),58784-58789.
MLA Tan, Jin,et al."Efficient synthesis of biofuel precursor with long carbon chains from fructose".RSC ADVANCES 5.72(2015):58784-58789.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Tan, Jin]'s Articles
[Liu, Qiying]'s Articles
[Cai, Chiliu]'s Articles
Baidu academic
Similar articles in Baidu academic
[Tan, Jin]'s Articles
[Liu, Qiying]'s Articles
[Cai, Chiliu]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Tan, Jin]'s Articles
[Liu, Qiying]'s Articles
[Cai, Chiliu]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.