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A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode
Wang, Jinglun1; Zhao, Xinyue1; Luo, Hao1; Yang, Jianwen2; Makoto, Yoshioka3; Zhang, Lingzhi1
2015-07-01
发表期刊ELECTROCHEMISTRY
卷号83期号:7页码:537-540
摘要An aminoalkyldisiloxane compound, (2-(N,N-dimethylamino)ethoxy)propyl pentamethyldisiloxane (DSC3N1), was investigated as a film-forming electrolyte additive for graphite anode. The graphite/Li cells with 1 vol% DSC3N1 addition exhibited superior electrochemical performances compared with those in the base electrolyte (1 M LiPF6 in EC/DEC; v/v = 1/1). The film-forming capability of DSC3N1 on the surface of graphite was investigated by scanning electron microscope, energy dispersive spectroscope, and FT-IR analysis. A comparative hydrolysis experiment of the electrolyte with/without DSC3N1 additive using F-19-NMR technique demonstrates that DSC3N1 exhibited acid scavenging property and inhibited the hydrolysis of LiPF6. (C) The Electrochemical Society of Japan, All rights reserved.
文章类型Article
关键词Aminoalkyldisiloxane Electrolyte Additive Graphite Anode Solid Electrolyte Interface
WOS标题词Science & Technology ; Physical Sciences
DOI10.5796/electrochemistry.83.537
研究领域[WOS]Electrochemistry
关键词[WOS]LITHIUM-ION BATTERIES ; LI-ION ; INFRARED-SPECTROSCOPY ; CELLS
收录类别SCI
语种英语
WOS类目Electrochemistry
WOS记录号WOS:000357767500004
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10522
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Guangxi, Peoples R China
3.North Altairnano Technol Co Ltd, Wuan 056300, Hebei, Peoples R China
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Wang, Jinglun,Zhao, Xinyue,Luo, Hao,et al. A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode[J]. ELECTROCHEMISTRY,2015,83(7):537-540.
APA Wang, Jinglun,Zhao, Xinyue,Luo, Hao,Yang, Jianwen,Makoto, Yoshioka,&Zhang, Lingzhi.(2015).A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode.ELECTROCHEMISTRY,83(7),537-540.
MLA Wang, Jinglun,et al."A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode".ELECTROCHEMISTRY 83.7(2015):537-540.
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