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A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode
Wang, Jinglun1; Zhao, Xinyue1; Luo, Hao1; Yang, Jianwen2; Makoto, Yoshioka3; Zhang, Lingzhi1
2015-07-01
Source PublicationELECTROCHEMISTRY
Volume83Issue:7Pages:537-540
AbstractAn aminoalkyldisiloxane compound, (2-(N,N-dimethylamino)ethoxy)propyl pentamethyldisiloxane (DSC3N1), was investigated as a film-forming electrolyte additive for graphite anode. The graphite/Li cells with 1 vol% DSC3N1 addition exhibited superior electrochemical performances compared with those in the base electrolyte (1 M LiPF6 in EC/DEC; v/v = 1/1). The film-forming capability of DSC3N1 on the surface of graphite was investigated by scanning electron microscope, energy dispersive spectroscope, and FT-IR analysis. A comparative hydrolysis experiment of the electrolyte with/without DSC3N1 additive using F-19-NMR technique demonstrates that DSC3N1 exhibited acid scavenging property and inhibited the hydrolysis of LiPF6. (C) The Electrochemical Society of Japan, All rights reserved.
SubtypeArticle
KeywordAminoalkyldisiloxane Electrolyte Additive Graphite Anode Solid Electrolyte Interface
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.5796/electrochemistry.83.537
WOS Subject ExtendedElectrochemistry
WOS KeywordLITHIUM-ION BATTERIES ; LI-ION ; INFRARED-SPECTROSCOPY ; CELLS
Indexed BySCI
Language英语
WOS SubjectElectrochemistry
WOS IDWOS:000357767500004
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10522
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Guangxi, Peoples R China
3.North Altairnano Technol Co Ltd, Wuan 056300, Hebei, Peoples R China
Recommended Citation
GB/T 7714
Wang, Jinglun,Zhao, Xinyue,Luo, Hao,et al. A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode[J]. ELECTROCHEMISTRY,2015,83(7):537-540.
APA Wang, Jinglun,Zhao, Xinyue,Luo, Hao,Yang, Jianwen,Makoto, Yoshioka,&Zhang, Lingzhi.(2015).A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode.ELECTROCHEMISTRY,83(7),537-540.
MLA Wang, Jinglun,et al."A Novel Aminoalkyldisiloxane Compound as a Film-Forming Electrolyte Additive for Graphite Anode".ELECTROCHEMISTRY 83.7(2015):537-540.
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