Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Phase diagram prediction of systems Mn(NO3)(2)-M(NO3)(n)-H2O (M=Ca, Mg and Li) with modified BET-model | |
Zeng, DW; Fan, SS; Chen, SH | |
2004-12-01 | |
发表期刊 | TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA |
卷号 | 14期号:6页码:1192-1198 |
摘要 | BET-model parameters for the binary system Mn(NO3)(2)-H2O were obtained by fitting experimental water activities at 298. 15 K. The values obtained in this work were compared to those fitted previously for the systems Ca(NO3)(2)-H2O and Zn(NO3)(2)-H2O, showing reasonable agreement. With the model parameters fitted at 298 K, the vapor pressure of the saturated solution for the phases Mn(NO3)(2) . 6H(2)O and Mn(NO3)(2) - 4H(2)O were predicted and shows quite good agreement with the experimental values. The phase diagram of the Mn(NO3)(2)-H2O SYStem reproduced by the BET model shows smaller deviation from the experimental data than that by the extended UNIQUAC model. The ternary phase diagrams of the systems Me(NO3)(n)-Mn(NO3)(2)-H2O (Me=Mg, Ca and Li) are predicted with the binary model parameter and compared with available experimental data, The predicted eutectic compositions were given as possible heat storage materials. |
文章类型 | Article |
关键词 | Activity Thermodynamic Model Solubility Manganous Nitrate Heat Storage Materials |
WOS标题词 | Science & Technology ; Technology |
研究领域[WOS] | Metallurgy & Metallurgical Engineering |
关键词[WOS] | MANGANOUS NITRATE-WATER ; CONCENTRATED-SOLUTIONS ; ELECTROLYTE ; TEMPERATURE ; THERMODYNAMICS ; HYDRATION ; SOLUBILITY ; MIXTURES |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000226333100026 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10487 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng, DW,Fan, SS,Chen, SH. Phase diagram prediction of systems Mn(NO3)(2)-M(NO3)(n)-H2O (M=Ca, Mg and Li) with modified BET-model[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2004,14(6):1192-1198. |
APA | Zeng, DW,Fan, SS,&Chen, SH.(2004).Phase diagram prediction of systems Mn(NO3)(2)-M(NO3)(n)-H2O (M=Ca, Mg and Li) with modified BET-model.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,14(6),1192-1198. |
MLA | Zeng, DW,et al."Phase diagram prediction of systems Mn(NO3)(2)-M(NO3)(n)-H2O (M=Ca, Mg and Li) with modified BET-model".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 14.6(2004):1192-1198. |
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