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Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface | |
Li, XJ; Li, FB; Gu, GB; Liu, S; Wang, LY; Liang, YY | |
2003-04-01 | |
发表期刊 | TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA |
卷号 | 13期号:2页码:448-451 |
摘要 | Based on the infrared characterization of methyl orange adsorption on TiO2 surface and the titration of TiO2, the triple layer model of methyl orange adsorption on TiO2 was established according to electric double theory. The software FITEQL3. 1 was applied to calculate the distribution of organic adsorption on TiO2 surface by introducing dummy components to help to overcome mathematical difficulties. It is shown that the chem. -adsorption species of methyl orange have a great adsorption amount. The adsorption constants of three kinds of surface complexation expressed as SOH+ org(-), SOH2 org(2) and SOHorg(-) are 5. 98, 17. 57 and - 4. 2, respectively. |
文章类型 | Article |
关键词 | Adsorption Methyl Orange Tio2 Surface Complexation Photocatalysis |
WOS标题词 | Science & Technology ; Technology |
研究领域[WOS] | Metallurgy & Metallurgical Engineering |
关键词[WOS] | PHOTO-CATALYTIC BEHAVIOR ; SEMICONDUCTOR NANOPOWDER ; TITANIUM-DIOXIDE ; INTERFACE |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000182726000044 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10469 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Peoples R China 2.Guangdong Inst Ecoenvironm & Soil Sci, Guangdong Key Lab Agr Environm Pollut Integrated, Guangzhou 510650, Peoples R China 3.S China Univ Technol, Dept Appl Chem, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Li, XJ,Li, FB,Gu, GB,et al. Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2003,13(2):448-451. |
APA | Li, XJ,Li, FB,Gu, GB,Liu, S,Wang, LY,&Liang, YY.(2003).Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,13(2),448-451. |
MLA | Li, XJ,et al."Photocatalytic reaction kinetics model based on electrical double layer theory - II. Surface complexation model of methyl orange adsorption on TiO2 surface".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 13.2(2003):448-451. |
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