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Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge
Tian, FJ; Li, BQ; Chen, Y; Li, CZ
2002-12-01
发表期刊FUEL
卷号81期号:17页码:2203-2208
摘要A sewage sludge sample from a wastewater treatment plant in China was pyrolysed in a fluidised-bed/fixed-bed reactor and in a fluidised-bed/tubular reactor. HCN was found to be the main NOx precursor, representing up to about 80% of the nitrogen present in the sludge. The thermal cracking of volatiles is the main route of HCN formation. NH3 was also an important NOx precursor formed during the pyrolysis of the sewage sludge. The experimental results indicate that there are at least two distinctive stages of NH3 formation during the pyrolysis of the sewage sludge at a fast heating rate. The formation of NH3 at temperatures lower than 400-500 degreesC is at least partly due to the amino structures in the sludge. The reactions of volatiles in the gas phase make negligible contributions to the observed NH3 yield. (C) 2002 Elsevier Science Ltd. All rights reserved.
文章类型Article
关键词Hcn Nh3 Nox Precursors Sewage Sludge And Pyrolysis
WOS标题词Science & Technology ; Technology
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]FLUIDIZED-BED ; SOX PRECURSORS ; WASTE MATERIALS ; HCN ; NH3 ; INCINERATION ; COMBUSTION ; CHEMICALS ; RELEASE ; REACTOR
收录类别SCI
语种英语
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000178414200009
引用统计
被引频次:132[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10456
专题中国科学院广州能源研究所
作者单位1.Monash Univ, CRC Clean Power Lignite, Clayton, Vic 3800, Australia
2.Chinese Acad Sco, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Shanxi, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Guangdong, Peoples R China
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GB/T 7714
Tian, FJ,Li, BQ,Chen, Y,et al. Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge[J]. FUEL,2002,81(17):2203-2208.
APA Tian, FJ,Li, BQ,Chen, Y,&Li, CZ.(2002).Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge.FUEL,81(17),2203-2208.
MLA Tian, FJ,et al."Formation of NOx precursors during the pyrolysis of coal and biomass. Part V. Pyrolysis of a sewage sludge".FUEL 81.17(2002):2203-2208.
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