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Structure of Ni/HZSM-5 Catalyst and Its Catalytic Performance for Aqueous Phase Hydrogenation of Sorbitol to Alkanes
Qiu Ke1,2; Zhang Qing1; Jiang Ting1,2; Ma Longlong1; Wang Tiejun1; Zhang Xinhua1,2; Qiu Minghuang1,2
2011-04-01
发表期刊CHINESE JOURNAL OF CATALYSIS
卷号32期号:4页码:612-617
摘要A bifunctional Ni/HZSM-5 catalyst was prepared by the conventional impregnation method. The effects of calcination temperature on the structure properties of the catalyst and its catalytic performance for aqueous phase hydrogenation of sorbitol were studied. The results showed that C(5)similar to C(6) alkanes were effectively obtained by the hydrogenation of the C-O bond in sorbitol and the following isomerization due to the synergism of the metal center and acid support. Moreover, the catalyst calcined at 500 degrees C exhibited a maximum value of 62.0% for sorbitol conversion and 76.4% of selectivity for pentane and hexane in comparison with other catalyst samples, wherein the isohexane selectivity was about 45.4%. The catalyst samples were characterized by N(2) physical adsorption, X-ray diffraction, NH(3) temperature-programmed desorption, and H(2) temperature-programmed reduction. It was found that the surface area and pore volume of the catalyst calcined at 500 degrees C were obviously increased. Smaller grains of NiO can be formed from the decomposition of nickel nitrate on the surface of HZSM-5, which can provide with the appropriate amounts of acid and the interaction between the nickel species and acid support for easier hydrogen reduction with the Ni reducibility of 100%. All these factors are closely related to the highest catalytic performance of Ni/HZSM-5 catalyst for aqueous phase hydrogenation of sorbitol.
文章类型Article
关键词Nickel Hzsm-5 Zeolite Sorbitol Aqueous Phase Hydrogenation Alkane
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.3724/SP.J.1088.2011.01016
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]RUTHENIUM CATALYSTS ; GAMMA-AL2O3 ; CONVERSION ; CELLOBIOSE ; PLATFORM ; GLUCOSE ; POLYOLS ; NICKEL ; STATE ; WATER
收录类别SCI
语种英语
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号WOS:000290074100014
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文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10388
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Qiu Ke,Zhang Qing,Jiang Ting,et al. Structure of Ni/HZSM-5 Catalyst and Its Catalytic Performance for Aqueous Phase Hydrogenation of Sorbitol to Alkanes[J]. CHINESE JOURNAL OF CATALYSIS,2011,32(4):612-617.
APA Qiu Ke.,Zhang Qing.,Jiang Ting.,Ma Longlong.,Wang Tiejun.,...&Qiu Minghuang.(2011).Structure of Ni/HZSM-5 Catalyst and Its Catalytic Performance for Aqueous Phase Hydrogenation of Sorbitol to Alkanes.CHINESE JOURNAL OF CATALYSIS,32(4),612-617.
MLA Qiu Ke,et al."Structure of Ni/HZSM-5 Catalyst and Its Catalytic Performance for Aqueous Phase Hydrogenation of Sorbitol to Alkanes".CHINESE JOURNAL OF CATALYSIS 32.4(2011):612-617.
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