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Preparation and Mechanism of Carbon Supported Pt Catalyst Using Pt (NO3)(2) and Ethylenediaminetetraacetic Acid
Xie Guo-Fang1; Lu Tian-Hong1,2; Yang Gai-Xiu3; Chen Yu1; Zhou Yi-Ming1; Tang Ya-Wen1,4
2011-06-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
Volume32Issue:6Pages:1373-1377
AbstractCarbon supported Pt(Pt/C) catalyst was prepared using Pt(NO3)(2) as the precursor and ethylenediaminetetraacetic acid(EDTA) as additive. The catalyst was characterized by X-ray diffraction(XRD) spectroscopy, transmission electron microscopy(TEM), ultraviolet visible(UV-Vis) absorption spectroscopy, Fourier transform infrared(FTIR) spectroscopy and electrochemical methods. The measurement results indicate that EDTA could not coordinate with Pt2+, forming the complex. However, EDTA would combine to Pt2+ through the electrostatic interaction, leading to that the Pt particles obtained are not easy to be aggregated. Thus, when Pt(NO3)(2) was used as the-precursor, EDTA can also effectively reduce the average size of the Pt particles and improve the dispersion degree. The average size of the Pt particles in the Pt/C catalyst obtained is only 3 nm and the dispersion of the Pt particles is uniform. Therefore, the Pt/C catalyst obtained has the excellent electrocatalytic activity and stability for methanol oxidation.
SubtypeArticle
KeywordPt/c Catalyst Ethylenediaminetetraacetic Acid(Edta) Direct Methanol Fuel Cell Electrostatic Interaction Methanol Oxidation
WOS HeadingsScience & Technology ; Physical Sciences
WOS Subject ExtendedChemistry
WOS KeywordFORMIC-ACID ; ELECTROCATALYTIC OXIDATION ; PD NANOPARTICLES ; POLYOL SYNTHESIS ; PARTICLE-SIZE ; FUEL-CELLS ; METHANOL ; ELECTROOXIDATION ; COMPOSITE ; PLATINUM
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000292178000027
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Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10365
Collection中国科学院广州能源研究所
Affiliation1.Nanjing Normal Univ, Sch Chem & Mat Sci, Nanjing 210097, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China
4.Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China
Recommended Citation
GB/T 7714
Xie Guo-Fang,Lu Tian-Hong,Yang Gai-Xiu,et al. Preparation and Mechanism of Carbon Supported Pt Catalyst Using Pt (NO3)(2) and Ethylenediaminetetraacetic Acid[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(6):1373-1377.
APA Xie Guo-Fang,Lu Tian-Hong,Yang Gai-Xiu,Chen Yu,Zhou Yi-Ming,&Tang Ya-Wen.(2011).Preparation and Mechanism of Carbon Supported Pt Catalyst Using Pt (NO3)(2) and Ethylenediaminetetraacetic Acid.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(6),1373-1377.
MLA Xie Guo-Fang,et al."Preparation and Mechanism of Carbon Supported Pt Catalyst Using Pt (NO3)(2) and Ethylenediaminetetraacetic Acid".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.6(2011):1373-1377.
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