Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synthesis Gas Production with NiO-MgO/gamma-Al2O3/Cordierite Monolithic Catalysts in a Pilot-Scale Biomass-Gasification-Reforming System | |
| Wang, Tiejun; Li, Yuping; Wang, Chenguang; Zhang, Xinghua; Ma, Longlong; Wu, Chuangzhi | |
| 2011-03-01 | |
| Source Publication | ENERGY & FUELS
 |
| Volume | 25Issue:3Pages:1221-1228 |
| Abstract | A pilot-scale biomass-gasification-reforming system (feedstock of 150-300 kg/h, on a dry basis) was established to produce synthesis gas for liquid fuel synthesis. The design and operation of this-system were preliminarily discussed. Reforming of biomass raw fuel gas over NiO-MgO/gamma-Al2O3/cordierite monolithic catalysts was investigated in a multi tube reformer. The anti coking and anti-sintering properties of NiO-MgO/gamma-Al2O3/cordierite monolithic catalysts were Characterized. The results showed that the NiO-MgO/gamma-Al2O3/cordierite monolithic catalyst with a pore channel size of 7 x 7 mm could continuously deal with biomass raw fuel gas containing large amounts of fly ash. NO channel blocking was observed for a long time running. The pressure drop, of the reformer was only below 700 Paeven under the conditions of fuel gas velocity of 1.4 m/s and fly ash content of 330 g N-1 m(-3) in the raw fuel gas. The synthesis gas [H-2 + CO > 60 vol %, H-2/CO ratio = 0.9-1.0, and lower heating value (LHV) > 10 MJ N-1 m(-3)], could be produced by the biomass-gasification-reforming process under the conditions of total equivalence ratio (ERT) of 0.27 (ERfirst of 0.23, ERsecond of 0.02, and ERthird of 0.02) and steam/biomass (S/B) ratio of 0.4. The cold gas efficiency was above 82%. The characterization of the spent catalysts thermogravimetic (TG), X-ray diffraction (XRD), and inductively coupled plasma-atomic emission spectrometry (ICP-AES) analyses indicated that the NiO-MgO solid solution structure in the catalyst could restrain the active Ni-0 centers from agglomeration and decrease carbon deposition. No serious alkali compound deposition on the surface of the catalyst was detected after the 60 h time-on-stream test. The pilot-scale biomass-gasification-reforming system exhibited excellent operation stability and flexibility. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Technology |
| DOI | 10.1021/ef1015268 |
| WOS Subject Extended | Energy & Fuels ; Engineering |
| WOS Keyword | STEAM-OXYGEN MIXTURES ; FLUIDIZED-BEDS ; NI CATALYSTS ; FUEL GAS ; DEACTIVATION ; EXPOSURE ; METHANE ; ELIMINATION ; REACTOR |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000289613300045 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10343 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Tiejun,Li, Yuping,Wang, Chenguang,et al. Synthesis Gas Production with NiO-MgO/gamma-Al2O3/Cordierite Monolithic Catalysts in a Pilot-Scale Biomass-Gasification-Reforming System[J]. ENERGY & FUELS,2011,25(3):1221-1228. |
| APA | Wang, Tiejun,Li, Yuping,Wang, Chenguang,Zhang, Xinghua,Ma, Longlong,&Wu, Chuangzhi.(2011).Synthesis Gas Production with NiO-MgO/gamma-Al2O3/Cordierite Monolithic Catalysts in a Pilot-Scale Biomass-Gasification-Reforming System.ENERGY & FUELS,25(3),1221-1228. |
| MLA | Wang, Tiejun,et al."Synthesis Gas Production with NiO-MgO/gamma-Al2O3/Cordierite Monolithic Catalysts in a Pilot-Scale Biomass-Gasification-Reforming System".ENERGY & FUELS 25.3(2011):1221-1228. |
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