Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Preparation and Characterization of Hydrogen Permeable Nb-Based Alloys | |
Luo Weimin1; Yan Changfeng1; Ishikawa, Kazuhiro2; Aoki, Kiyoshi2 | |
2010-06-01 | |
发表期刊 | RARE METAL MATERIALS AND ENGINEERING |
卷号 | 39期号:6页码:1045-1049 |
摘要 | Pd-Ag alloy shows high hydrogen permeability and excellent resistance to hydrogen embrittlement, so it is used to separate the products of methane steam reforming to achieve high purity hydrogen. However, Pd is very expensive; therefore it is eagerly desired to develop no-Pd based alloys with low cost and high hydrogen permeation performance. In order to find out Nb-Ti-Ni alloy with higher hydrogen permeability, the Nb-Ti-Ni alloys located at the straight line connecting the primary (Nb, Ti) of Nb40Ti30Ni30 and the eutectic {(Nb,Ti)+TiNi} phases in the Nb-Ti-Ni trinary diagram were prepared. Results show that the alloys located at the straight line consists of the primary (Nb, Ti) and the eutectic {(Nb,Ti)+TiNi} phases, and their hydrogen permeability increase with increasing of Nb content or volume fraction of the primary (Nb,Ti). Moreover, the Nb content increases to 68 mol%. The Nb68Ti17Ni15 alloy, consisting of 74 vol% primary (Nb, Ti) phase and 26 vol% eutectic {(Nb,Ti)+TiNi} phase, show the highest Phi(673K) of 4.91 x 10(-8) mol H(2)m(-1)s(-1)Pa(-0.5), which is 2.5 times as high as that of the Nb40Ti30Ni30, and 3.5 times as high as that of the pure Pd. |
文章类型 | Article |
关键词 | Hydrogen Permeable Alloy Nb-based Alloy Hydrogen Permeability Microstructure |
WOS标题词 | Science & Technology ; Technology |
研究领域[WOS] | Materials Science ; Metallurgy & Metallurgical Engineering |
关键词[WOS] | PERMEATION CHARACTERISTICS ; MEMBRANES ; SEPARATION |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000281248300024 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10332 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.China Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Kitami Inst Technol, Kitami, Hokkaido 0908507, Japan |
推荐引用方式 GB/T 7714 | Luo Weimin,Yan Changfeng,Ishikawa, Kazuhiro,et al. Preparation and Characterization of Hydrogen Permeable Nb-Based Alloys[J]. RARE METAL MATERIALS AND ENGINEERING,2010,39(6):1045-1049. |
APA | Luo Weimin,Yan Changfeng,Ishikawa, Kazuhiro,&Aoki, Kiyoshi.(2010).Preparation and Characterization of Hydrogen Permeable Nb-Based Alloys.RARE METAL MATERIALS AND ENGINEERING,39(6),1045-1049. |
MLA | Luo Weimin,et al."Preparation and Characterization of Hydrogen Permeable Nb-Based Alloys".RARE METAL MATERIALS AND ENGINEERING 39.6(2010):1045-1049. |
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