Direct synthesis of isopaxaffin from synthesis gas under supercritical conditions

doi:10.1016/j.cattod.2009.03.021

GIEC OpenIR > 中国科学院广州能源研究所

	Direct synthesis of isopaxaffin from synthesis gas under supercritical conditions
	Yoneyama, Yoshiharu 1; Sun, Xiaoyu 2; Zhao, Tiansheng 3; Wang, Tiejun 4; Iwai, Toshiaki 1; Ozaki, Koichi 1; Tsubaki, Noritatsu 1,5
	2010-01-15
发表期刊	CATALYSIS TODAY
卷号	149 期号:1-2 页码:105-110
摘要	To produce isoparaffins from synthesis gas directly, modified Fischer-Tropsch (FT)synthesis was carried out under supercritical conditions using n-butane as a medium. One-step FT synthesis using a hybrid catalyst consisting Of Co/SiO(2), HZSM-5 and Pd/SiO(2) was carried Out Introduction of supercritical-phase n-butane increased light isoparaffins significantly and suppressed the formation of the by-product, methane. Under supercritical-phase butane. hydrogenolysis and isomerization reactions were promoted. Due to the fact that the optimum temperatures for FT and HZSM-5 catalysts are different. 513 K and over 573 K, respectively. two-step FT synthesis was also carried Out to optimize the reaction temperatures. The first-step reaction used Co/SiO(2) catalyst containing small amount of HZSM-5 for FT synthesis at 513 K, and the second-step reaction used a hybrid catalyst containing Pd/SiO(2) and zeolite for hydrogenolysis and isomerization of hydrocarbons at 573 K Introduction of supercritical n-butane increased the isoparaffin selectivity, and decreased the methane selectivity significantly. The production of heavy hydrocarbons C(9)(+) was inhibited in both gas and supercritical phase. The isoparaffin selectivity in the gas phase decreased with time-on-stream, but very stable for the supercritical-phase reaction Because water and heavy hydrocarbons were removed from active sites on zeolite and the zeolite acidity was promoted in the supercritical medium. the selectivity of isoparaffin was considered stable Among zeolites added to the hybrid catalyst in the second-step reactor. HZSM-5 and H-beta zeolite were suitable for producing light isoparaffins. These results indicated that two-step FT synthesis under supercritical n-butane was superior for producing light isoparaffins from synthesis gas directly. (C) 2009 Elsevier B.V. All rights reserved
文章类型	Article
关键词	Fischer-tropsch Synthesis Hzsm-5 Supercritical Conditions
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1016/j.cattod.2009.03.021
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	FISCHER-TROPSCH SYNTHESIS ; HYBRID CATALYST ; ISOPARAFFIN
收录类别	SCI ; ISTP
语种	英语
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号	WOS:000274145600016
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10323
专题	中国科学院广州能源研究所
作者单位	1.Toyama Univ, Grad Sch Engn, Dept Environm Appl Chem, Toyama 9308555, Japan 2.China Univ Petr, Dongying 257061, Shandong, Peoples R China 3.Ningxia Univ, Ningxia 750021, Peoples R China 4.CAS, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 5.CREST, JST, Chiyoda Ku, Tokyo 1020075, Japan
推荐引用方式 GB/T 7714	Yoneyama, Yoshiharu,Sun, Xiaoyu,Zhao, Tiansheng,et al. Direct synthesis of isopaxaffin from synthesis gas under supercritical conditions[J]. CATALYSIS TODAY,2010,149(1-2):105-110.
APA	Yoneyama, Yoshiharu.,Sun, Xiaoyu.,Zhao, Tiansheng.,Wang, Tiejun.,Iwai, Toshiaki.,...&Tsubaki, Noritatsu.(2010).Direct synthesis of isopaxaffin from synthesis gas under supercritical conditions.CATALYSIS TODAY,149(1-2),105-110.
MLA	Yoneyama, Yoshiharu,et al."Direct synthesis of isopaxaffin from synthesis gas under supercritical conditions".CATALYSIS TODAY 149.1-2(2010):105-110.