GIEC OpenIR  > 中国科学院广州能源研究所
Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported on SiO(2)/HZSM-5
Li, Yuping1,2; Wang, Tiejun1,2; Wu, Chuangzhi1,2; Lv, Yongxing1,2,3; Tsubaki, Noritatsu4
2008-05-01
发表期刊ENERGY & FUELS
卷号22期号:3页码:1897-1901
摘要Two types of SiO(2) with different mesopore size and HZSM-5 zeolite were used to prepare hybrid supported cobalt-based catalysts. The textual and structural properties of the catalysts were studied using N(2) physisorption, X-ray diffraction (XRD), and H(2) temperature-programmed reduction (TPR) techniques. Fischer-Tropsch synthesis (FTS) performances of the catalysts were carried out in a fixed-bed reactor. The combination effects of the meso- and micropores of the supports as well as the interaction between supports and cobalt particles on FTS activity are discussed. The results indicate that the catalyst supported on the tailor-made SiO(2) and HZSM-5 hybrid maintained both meso- and micropore pores during the preparation process without HZSM-5 particles agglomerating. The mesopores provided quick mass transfer channels, while the micropores contributed to high metal dispersion and accelerated hydrocracking/hydroisomerization reaction rate. High CO conversion of 83.9% and selectivity to gasoline-range hydrocarbons (C(5)-C(12)) of 55%, including more than 10% isoparaffins, were achieved simultaneously on this type of catalyst.
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/ef700625z
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]BIMODAL PORE CATALYSTS ; SYNGAS ; CO ; CONVERSION ; OXIDATION ; PROMOTER ; ZEOLITE ; IMPACT ; HZSM-5
收录类别SCI
语种英语
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000256057600065
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10290
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
4.Toyama Univ, Dept Appl Chem, Sch Engn, Toyama 9308555, Japan
推荐引用方式
GB/T 7714
Li, Yuping,Wang, Tiejun,Wu, Chuangzhi,et al. Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported on SiO(2)/HZSM-5[J]. ENERGY & FUELS,2008,22(3):1897-1901.
APA Li, Yuping,Wang, Tiejun,Wu, Chuangzhi,Lv, Yongxing,&Tsubaki, Noritatsu.(2008).Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported on SiO(2)/HZSM-5.ENERGY & FUELS,22(3),1897-1901.
MLA Li, Yuping,et al."Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported on SiO(2)/HZSM-5".ENERGY & FUELS 22.3(2008):1897-1901.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Li, Yuping]的文章
[Wang, Tiejun]的文章
[Wu, Chuangzhi]的文章
百度学术
百度学术中相似的文章
[Li, Yuping]的文章
[Wang, Tiejun]的文章
[Wu, Chuangzhi]的文章
必应学术
必应学术中相似的文章
[Li, Yuping]的文章
[Wang, Tiejun]的文章
[Wu, Chuangzhi]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。