Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate | |
Xu, X. Q.; Shen, H.; Xu, J. R.; Xie, M. Q.; Li, X. J. | |
2006-12-15 | |
发表期刊 | APPLIED SURFACE SCIENCE |
卷号 | 253期号:4页码:2158-2164 |
摘要 | The adsorption of alginate (Alg) onto the surface of in water dispersed Fe3O4 nanoparticles and zeta potential of alginate-coated Fe3O4 nanoparticles have been investigated to optimize the colloidal stability of Alg-coated Fe3O4 nanoparticles. The adsorption amount of Alg increased with the decrease of adsorption pH. The zeta potential of Fe3O4 nanoparticles shifted to a lower value after adsorption of Alg. The lower adsorption pH was the lower zeta potential of Fe3O4 nanoparticles became. The Alg-coated Fe3O4 nanoparticles were found to be stabilized by steric and electrostatic repulsions. Those prepared at pH 6 were not stable around pH 5, and those prepared at pH 4 became unstable at pH below 3.5. Alg of M-w 45 kDa was a little bit more adsorbed onto nanoparticles surface than that of Mw 24 kDa. An average Fe3O4 core size of 9.3 +/- 1.7 nm was found by transmission electronic microscopy. An average hydrodynamic diameter of 30-150 nm was measured by photon correlation spectroscopy. However, an average core size of 10 rim and an average hydrodynamic diameter of 38 nm were estimated from the magnetization curve of the concentrated magnetic fluids (MFs). The maximum available saturation magnetization of MFs was about 3.5 kA/m. (c) 2006 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Magnetite Nanoparticles Alginate Adsorption Zeta Potential Stability Structure |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.apsusc.2006.04.015 |
研究领域[WOS] | Chemistry ; Materials Science ; Physics |
关键词[WOS] | SURFACE ; POLYMER |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
WOS记录号 | WOS:000243244200080 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10261 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Sun Yat Sen Univ, Sch Phys & Engn, Guangzhou 510275, Peoples R China 3.Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China 4.Sun Yat Sen Univ, Affiliated Hosp 3, Guangzhou 510630, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, X. Q.,Shen, H.,Xu, J. R.,et al. The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate[J]. APPLIED SURFACE SCIENCE,2006,253(4):2158-2164. |
APA | Xu, X. Q.,Shen, H.,Xu, J. R.,Xie, M. Q.,&Li, X. J..(2006).The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate.APPLIED SURFACE SCIENCE,253(4),2158-2164. |
MLA | Xu, X. Q.,et al."The colloidal stability and core-shell structure of magnetite nanoparticles coated with alginate".APPLIED SURFACE SCIENCE 253.4(2006):2158-2164. |
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