Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst

doi:10.1016/j.matchemphys.2005.01.030

GIEC OpenIR > 中国科学院广州能源研究所

	Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst
	Xu, YH ; Wang, LY ; Zhang, Q ; Zheng, SH ; Li, XJ ; Huang, C
	2005-08-15
发表期刊	MATERIALS CHEMISTRY AND PHYSICS
卷号	92 期号:2-3 页码:470-474
摘要	The sulfated TiO2 were prepared by dipping TiO2 in H2SO4 solutions. The reactivity of methylene blue photocatalytic degradation of all SO42-/TiO2 are higher than that of TiO2, and the optimum molar concentration of SO42- on TiO2 is 9%. IR confirmed that the chelating bidentate SO42- and unidentate SO42- coexist in SO42-/TiO2. Methylene blue is cationic dye. Maybe the Lewis acid and Bronsted acid coexist in the SO42-/TiO2 catalyst, the adsorption of methylene blue on the catalyst increases. The high photocatalytic reactivity of SO42-/TiO2 is consistent with the good adsorption. The presence of SO42- enhances the light absorption in the visible region of SO42-/TiO2, and the photocatalytic activity of SO42-/TiO2 correlates with reflectance of the samples in the visible light region. The fluorescence spectra show that weaker the fluorescence intensity the higher the activity. Thus, The enhanced photocatalytic activity of SO42-/TiO2 may be explained by the good adsorption of methylene blue on the catalysts, high light absorption in the visible region, and weak fluorescence intensity. © 2005 Elsevier B.V. All rights reserved.
文章类型	Article
关键词	Methylene Blue So42-/tio2 Photocatalytic Degradation
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.matchemphys.2005.01.030
研究领域[WOS]	Materials Science
关键词[WOS]	ION
收录类别	SCI
语种	英语
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000229103900029
引用统计	被引频次：24[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10240
专题	中国科学院广州能源研究所
作者单位	1.S China Agr Univ, Coll Sci, Guangzhou 510642, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510070, Peoples R China
推荐引用方式 GB/T 7714	Xu, YH,Wang, LY,Zhang, Q,et al. Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst[J]. MATERIALS CHEMISTRY AND PHYSICS,2005,92(2-3):470-474.
APA	Xu, YH,Wang, LY,Zhang, Q,Zheng, SH,Li, XJ,&Huang, C.(2005).Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst.MATERIALS CHEMISTRY AND PHYSICS,92(2-3),470-474.
MLA	Xu, YH,et al."Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst".MATERIALS CHEMISTRY AND PHYSICS 92.2-3(2005):470-474.