Characteristics of the synthesis of methanol using biomass-derived syngas

doi:10.1021/ef0498622

GIEC OpenIR > 中国科学院广州能源研究所

	Characteristics of the synthesis of methanol using biomass-derived syngas
	Yin, XL ; Leung, DYC ; Chang, J ; Wang, JF ; Fu, Y ; Wu, CZ
	2005
发表期刊	ENERGY & FUELS
卷号	19 期号:1 页码:305-310
摘要	The characteristics of methanol synthesis from biomass-derived syngas were studied in a high-pressure microreactor with a commercial Cu/ZnO/Al2O3 catalyst. A series of experiments was conducted at a temperature range of 215-270degreesC, with three different pressures of 2.6, 3.6. and 4.6 MPa and space velocities of 4000-12000 h(-1). Four model bio-syngases with different H-2/CO/CO2/N-2 ratios, which were configured according to the results of biomass gasification, were used in the studies. The effect of temperature, pressure, and space velocity on the space-time yield and selectivity of methanol was explored. The sensitivity analysis of the yield and selectivity of methanol with different H2/(CO + CO2) and CO2/CO ratios was investigated. Results show that both yield and selectivity of methanol are affected by the operating parameters, and optimum conditions exist within the tested range. The yield of methanol is sensitive to the H-2/(CO + CO2,) ratio, whereas the selectivity of methanol is more sensitive to the CO2/CO ratio. It is concluded that the yield of methanol from the syngas derived from air-steam gasification is lower than that from catalytic gasification, whereas the selectivity of methanol is the reverse. With a partial removal of CO2, both yield and selectivity of methanol can be improved.
文章类型	Article
WOS标题词	Science & Technology ; Technology
DOI	10.1021/ef0498622
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	HYDROGEN-RICH GAS ; CU/ZNO/AL2O3 CATALYST ; GASIFICATION ; CO ; BED
收录类别	SCI
语种	英语
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000226471300039
引用统计	被引频次：66[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10235
专题	中国科学院广州能源研究所
作者单位	1.Univ Hong Kong, Dept Engn Mech, Hong Kong, Hong Kong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Yin, XL,Leung, DYC,Chang, J,et al. Characteristics of the synthesis of methanol using biomass-derived syngas[J]. ENERGY & FUELS,2005,19(1):305-310.
APA	Yin, XL,Leung, DYC,Chang, J,Wang, JF,Fu, Y,&Wu, CZ.(2005).Characteristics of the synthesis of methanol using biomass-derived syngas.ENERGY & FUELS,19(1),305-310.
MLA	Yin, XL,et al."Characteristics of the synthesis of methanol using biomass-derived syngas".ENERGY & FUELS 19.1(2005):305-310.