Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate | |
Huang, Jing1,2; Li, Hongmiao1; Zhang, Jianyong1; Jiang, Long1; Su, Cheng-Yong1 | |
2012-06-15 | |
发表期刊 | INORGANICA CHIMICA ACTA |
卷号 | 388页码:16-21 |
摘要 | The N,O ligand, namely 5-(pyridin-4-yl)isophthalic acid (LH2), with carboxylic acid groups and pyridyl group separated, prefers to act as a bridging ligand. Its Tb(III) coordination polymer, [TbL(LH)(H2O)(2)](infinity)center dot xH(2)O (1), and heterometallic Tb(III)-Ni(II) coordination polymer, [TbNiL2(LH)(H2O)](infinity)center dot xH(2)O (2), have been successfully prepared. Complex 1 exhibits a two-dimensional layered structure with (4,4) network leaving all the pyridyl N-donors uncoordinated, while complex 2 has a three-dimensional structure due to coordination of Ni(II) to part of pyridyl N-donors. Both the complexes were characterized by single-crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry analysis. The ligand is capable of sensitizing the Tb(III) ion, and both the complexes emit characteristic visible green luminescence of Tb(III). (C) 2012 Elsevier B. V. All rights reserved. |
文章类型 | Article |
关键词 | Coordination Polymers Heterometallic Complexes n Crystal Structures o Ligands Luminescence |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.ica.2012.03.004 |
研究领域[WOS] | Chemistry |
关键词[WOS] | METAL-ORGANIC FRAMEWORK ; CATALYTICALLY ACTIVE-SITES ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURES ; BUILDING-BLOCK ; SOFT ACIDS ; COMPLEXES ; LIGANDS ; ZINC ; METALLOLIGAND |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Inorganic & Nuclear |
WOS记录号 | WOS:000304244500003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10182 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Environm Energy & Mat Lab, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, Jing,Li, Hongmiao,Zhang, Jianyong,et al. Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate[J]. INORGANICA CHIMICA ACTA,2012,388:16-21. |
APA | Huang, Jing,Li, Hongmiao,Zhang, Jianyong,Jiang, Long,&Su, Cheng-Yong.(2012).Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate.INORGANICA CHIMICA ACTA,388,16-21. |
MLA | Huang, Jing,et al."Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate".INORGANICA CHIMICA ACTA 388(2012):16-21. |
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