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Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate
Huang, Jing1,2; Li, Hongmiao1; Zhang, Jianyong1; Jiang, Long1; Su, Cheng-Yong1
2012-06-15
发表期刊INORGANICA CHIMICA ACTA
卷号388页码:16-21
摘要

The N,O ligand, namely 5-(pyridin-4-yl)isophthalic acid (LH2), with carboxylic acid groups and pyridyl group separated, prefers to act as a bridging ligand. Its Tb(III) coordination polymer, [TbL(LH)(H2O)(2)](infinity)center dot xH(2)O (1), and heterometallic Tb(III)-Ni(II) coordination polymer, [TbNiL2(LH)(H2O)](infinity)center dot xH(2)O (2), have been successfully prepared. Complex 1 exhibits a two-dimensional layered structure with (4,4) network leaving all the pyridyl N-donors uncoordinated, while complex 2 has a three-dimensional structure due to coordination of Ni(II) to part of pyridyl N-donors. Both the complexes were characterized by single-crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry analysis. The ligand is capable of sensitizing the Tb(III) ion, and both the complexes emit characteristic visible green luminescence of Tb(III). (C) 2012 Elsevier B. V. All rights reserved.

文章类型Article
关键词Coordination Polymers Heterometallic Complexes n Crystal Structures o Ligands Luminescence
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.ica.2012.03.004
研究领域[WOS]Chemistry
关键词[WOS]METAL-ORGANIC FRAMEWORK ; CATALYTICALLY ACTIVE-SITES ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURES ; BUILDING-BLOCK ; SOFT ACIDS ; COMPLEXES ; LIGANDS ; ZINC ; METALLOLIGAND
收录类别SCI
语种英语
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000304244500003
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10182
专题中国科学院广州能源研究所
作者单位1.Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Environm Energy & Mat Lab, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Huang, Jing,Li, Hongmiao,Zhang, Jianyong,et al. Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate[J]. INORGANICA CHIMICA ACTA,2012,388:16-21.
APA Huang, Jing,Li, Hongmiao,Zhang, Jianyong,Jiang, Long,&Su, Cheng-Yong.(2012).Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate.INORGANICA CHIMICA ACTA,388,16-21.
MLA Huang, Jing,et al."Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate".INORGANICA CHIMICA ACTA 388(2012):16-21.
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