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Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate
Huang, Jing1,2; Li, Hongmiao1; Zhang, Jianyong1; Jiang, Long1; Su, Cheng-Yong1
2012-06-15
Source PublicationINORGANICA CHIMICA ACTA
Volume388Pages:16-21
Abstract

The N,O ligand, namely 5-(pyridin-4-yl)isophthalic acid (LH2), with carboxylic acid groups and pyridyl group separated, prefers to act as a bridging ligand. Its Tb(III) coordination polymer, [TbL(LH)(H2O)(2)](infinity)center dot xH(2)O (1), and heterometallic Tb(III)-Ni(II) coordination polymer, [TbNiL2(LH)(H2O)](infinity)center dot xH(2)O (2), have been successfully prepared. Complex 1 exhibits a two-dimensional layered structure with (4,4) network leaving all the pyridyl N-donors uncoordinated, while complex 2 has a three-dimensional structure due to coordination of Ni(II) to part of pyridyl N-donors. Both the complexes were characterized by single-crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry analysis. The ligand is capable of sensitizing the Tb(III) ion, and both the complexes emit characteristic visible green luminescence of Tb(III). (C) 2012 Elsevier B. V. All rights reserved.

SubtypeArticle
KeywordCoordination Polymers Heterometallic Complexes n Crystal Structures o Ligands Luminescence
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.ica.2012.03.004
WOS Subject ExtendedChemistry
WOS KeywordMETAL-ORGANIC FRAMEWORK ; CATALYTICALLY ACTIVE-SITES ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURES ; BUILDING-BLOCK ; SOFT ACIDS ; COMPLEXES ; LIGANDS ; ZINC ; METALLOLIGAND
Indexed BySCI
Language英语
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000304244500003
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10182
Collection中国科学院广州能源研究所
Affiliation1.Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, Guangzhou 510275, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Environm Energy & Mat Lab, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Huang, Jing,Li, Hongmiao,Zhang, Jianyong,et al. Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate[J]. INORGANICA CHIMICA ACTA,2012,388:16-21.
APA Huang, Jing,Li, Hongmiao,Zhang, Jianyong,Jiang, Long,&Su, Cheng-Yong.(2012).Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate.INORGANICA CHIMICA ACTA,388,16-21.
MLA Huang, Jing,et al."Structures and luminescent properties of Tb(III) and Tb(III)-Ni(II) coordination polymers based on pyridyl dicarboxylate".INORGANICA CHIMICA ACTA 388(2012):16-21.
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