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Upgrading of fast pyrolysis liquid fuel from biomass over Ru/gamma-Al2O3 catalyst
Xu Ying1,2,3; Wang Tiejun1,3; Ma Longlong1,3; Chen Guanyi2
2012-03-01
Source PublicationENERGY CONVERSION AND MANAGEMENT
Volume55Pages:172-177
Abstract

Biomass is one of the important renewable energy. More attention has been paid on conversion of biomass and the upgrading of its products. In this paper, the bio-oil was prepared by pyrolysis of pine sawdust in fast pyrolysis installation. A series of ruthenium catalysts were prepared for the upgrading of bio-oil. The catalytic activity was evaluated by the reaction of the model compound (acetic acid) under 3 MPa hydrogen pressure. The effects of Ru-loading and second metal addition on the catalytic activity were investigated. The 0.5Ru/gamma-Al2O3 catalyst with 0.5%Co addition exhibited the highest activity, giving the highest conversion of acetic acid (30.98%). After upgrading over this catalyst, the properties of the pyrolysis bio-oil were improved. The content of the esters increased by 2-fold in the upgraded oil than in the raw one. The GC-MS spectrometry analysis showed that not only the hydrogenation but also the esterification happened in the bio-oil over the CoRu/gamma-Al2O3 catalyst. Results indicate that it is possible to improve the properties of bio-oil by hydrotreating and esterifying carboxyl groups. (C) 2011 Elsevier Ltd. All rights reserved.

SubtypeArticle
KeywordBiomass Fast Pyrolysis Bio-oil Upgrading Ru/gamma-al2o3
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.enconman.2011.10.016
WOS Subject ExtendedThermodynamics ; Energy & Fuels ; Mechanics ; Physics
WOS KeywordBIO-OIL ; CONVERSION ; PRESSURE ; HYDROGEN
Indexed BySCI
Language英语
WOS SubjectThermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear
WOS IDWOS:000301217200018
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10173
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Tianjin Univ, Sch Environm Sci & Technol, State Key Lab Engines, Tianjin, Peoples R China
3.CAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Xu Ying,Wang Tiejun,Ma Longlong,et al. Upgrading of fast pyrolysis liquid fuel from biomass over Ru/gamma-Al2O3 catalyst[J]. ENERGY CONVERSION AND MANAGEMENT,2012,55:172-177.
APA Xu Ying,Wang Tiejun,Ma Longlong,&Chen Guanyi.(2012).Upgrading of fast pyrolysis liquid fuel from biomass over Ru/gamma-Al2O3 catalyst.ENERGY CONVERSION AND MANAGEMENT,55,172-177.
MLA Xu Ying,et al."Upgrading of fast pyrolysis liquid fuel from biomass over Ru/gamma-Al2O3 catalyst".ENERGY CONVERSION AND MANAGEMENT 55(2012):172-177.
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