Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation | |
Zhang, Xinghua1,2; Wang, Tiejun1; Ma, Longlong1; Zhang, Qi1; Yu, Yuxiao1,2; Liu, Qiying1 | |
2013-03-05 | |
发表期刊 | CATALYSIS COMMUNICATIONS |
卷号 | 33页码:15-19 |
摘要 | ZrO2-SiO2 complex oxides with Si/Zr mole ratio of 3 (SZ-3) were synthesized. ZrO2-SiO2 supported Ni and NiCu catalysts were prepared by impregnation method. Their catalytic performances were evaluated in the hydrodeoxygenation (HDO) upgrading of model reactant guaiacol to hydrocarbons. The physicochemical properties of the support materials and catalysts were characterized by FTIR, XRD, TPD, TPR, and BET techniques. The addition of Cu significantly affected the acidity, and thus influenced their catalytic performance for product distributions. Over the Ni5Cu/SZ-3 catalyst, the cyclohexane selectivity of 80.8% and the methylcyclohexane selectivity of 12.4% were obtained with complete conversion of guaiacol under the 300 degrees C, 5.0 MPa H-2 pressure. (C) 2012 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Catalyst Zro2-sio2 Guaiacol Hydrodeoxygenation (Hdo) |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.catcom.2012.12.011 |
研究领域[WOS] | Chemistry |
关键词[WOS] | NOBLE-METAL CATALYSTS ; PYROLYSIS OIL ; LIGNIN ; BENZOFURAN ; NICKEL |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000316583700004 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10125 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,et al. Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation[J]. CATALYSIS COMMUNICATIONS,2013,33:15-19. |
APA | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,Zhang, Qi,Yu, Yuxiao,&Liu, Qiying.(2013).Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation.CATALYSIS COMMUNICATIONS,33,15-19. |
MLA | Zhang, Xinghua,et al."Characterization and catalytic properties of Ni and NiCu catalysts supported on ZrO2-SiO2 for guaiacol hydrodeoxygenation".CATALYSIS COMMUNICATIONS 33(2013):15-19. |
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