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Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source
Chen, Aibing1; Li, Yonglei1,2; Chen, Jinzhu2; Zhao, Guoying1,2; Ma, Longlong2; Yu, Yifeng1
2013-11-01
发表期刊CHEMPLUSCHEM
卷号78期号:11页码:1370-1378
摘要Selective hydrogenation of phenol to cyclohexanone over a catalyst of polyaniline-functionalized carbon-nanofiber-supported palladium (Pd-PANI/CNF) with sodium formate as the hydrogen source has been studied. Phenol conversion exceeding 99% was achieved with a cyclohexanone selectivity of >99% in aqueous media. In an extension to Pd-PANI/CNF, polymers such as polypyrrole (PPY), poly(4-vinylpyridine) (PVP), and poly(1-vinylimidazole) (PVI) were further applied to a catalyst of Pd-polymer/CNF for selective phenol hydrogenation. All of the Pd-polymer/CNF catalysts showed excellent to good performance toward selective phenol hydrogenation. However, Pd-PANI/CNF was considerably more active and selective to afford the desired cyclohexanone than Pd-PPY/CNF, Pd-PVP/CNF, and Pd-PVI/CNF. Moreover, a series of phenol-derived compounds were selectively hydrogenated in high yields under the investigated aqueous conditions. The research highlights an environmentally benign and effective process for the selective reduction of phenol derivatives with sodium formate as an alternative hydrogen source.
文章类型Article
关键词Hydrogenation Nanostructures Palladium Polymers Sodium Formate
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/cplu.201300238
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC TRANSFER HYDROGENATION ; AQUEOUS-MEDIA ; CATALYSTS ; NANOTUBES ; WATER ; POLYANILINE ; OXIDATION ; NANOPARTICLES ; DIOXIDE ; DEHYDROGENATION
收录类别SCI ; CCR
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000326900600013
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10120
专题中国科学院广州能源研究所
作者单位1.Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CSA Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
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Chen, Aibing,Li, Yonglei,Chen, Jinzhu,et al. Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source[J]. CHEMPLUSCHEM,2013,78(11):1370-1378.
APA Chen, Aibing,Li, Yonglei,Chen, Jinzhu,Zhao, Guoying,Ma, Longlong,&Yu, Yifeng.(2013).Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source.CHEMPLUSCHEM,78(11),1370-1378.
MLA Chen, Aibing,et al."Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source".CHEMPLUSCHEM 78.11(2013):1370-1378.
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