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Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source
Chen, Aibing1; Li, Yonglei1,2; Chen, Jinzhu2; Zhao, Guoying1,2; Ma, Longlong2; Yu, Yifeng1
2013-11-01
Source PublicationCHEMPLUSCHEM
Volume78Issue:11Pages:1370-1378
AbstractSelective hydrogenation of phenol to cyclohexanone over a catalyst of polyaniline-functionalized carbon-nanofiber-supported palladium (Pd-PANI/CNF) with sodium formate as the hydrogen source has been studied. Phenol conversion exceeding 99% was achieved with a cyclohexanone selectivity of >99% in aqueous media. In an extension to Pd-PANI/CNF, polymers such as polypyrrole (PPY), poly(4-vinylpyridine) (PVP), and poly(1-vinylimidazole) (PVI) were further applied to a catalyst of Pd-polymer/CNF for selective phenol hydrogenation. All of the Pd-polymer/CNF catalysts showed excellent to good performance toward selective phenol hydrogenation. However, Pd-PANI/CNF was considerably more active and selective to afford the desired cyclohexanone than Pd-PPY/CNF, Pd-PVP/CNF, and Pd-PVI/CNF. Moreover, a series of phenol-derived compounds were selectively hydrogenated in high yields under the investigated aqueous conditions. The research highlights an environmentally benign and effective process for the selective reduction of phenol derivatives with sodium formate as an alternative hydrogen source.
SubtypeArticle
KeywordHydrogenation Nanostructures Palladium Polymers Sodium Formate
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/cplu.201300238
WOS Subject ExtendedChemistry
WOS KeywordASYMMETRIC TRANSFER HYDROGENATION ; AQUEOUS-MEDIA ; CATALYSTS ; NANOTUBES ; WATER ; POLYANILINE ; OXIDATION ; NANOPARTICLES ; DIOXIDE ; DEHYDROGENATION
Indexed BySCI ; CCR
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000326900600013
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10120
Collection中国科学院广州能源研究所
Affiliation1.Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CSA Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Chen, Aibing,Li, Yonglei,Chen, Jinzhu,et al. Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source[J]. CHEMPLUSCHEM,2013,78(11):1370-1378.
APA Chen, Aibing,Li, Yonglei,Chen, Jinzhu,Zhao, Guoying,Ma, Longlong,&Yu, Yifeng.(2013).Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source.CHEMPLUSCHEM,78(11),1370-1378.
MLA Chen, Aibing,et al."Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source".CHEMPLUSCHEM 78.11(2013):1370-1378.
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