Oligo(ethylene oxide)-functionalized trialkoxysilanes as novel electrolytes for high-voltage lithium-ion batteries

doi:10.1007/s11581-013-0888-z

GIEC OpenIR > 中国科学院广州能源研究所

	Oligo(ethylene oxide)-functionalized trialkoxysilanes as novel electrolytes for high-voltage lithium-ion batteries
	Qin, Xueying 1,2; Wang, Jinglun1 ; Mai, Yongjin 1; Tang, Daoping 1; Zhao, Xinyue 1; Zhang, Lingzhi1
	2013-11-01
发表期刊	IONICS
卷号	19 期号:11 页码:1567-1572
摘要	Oligo(ethylene oxide)-functionalized trialkoxysilanes were synthesized through hydrosilylation reaction by reacting trialkoxysilane with oligo(ethylene oxide) allyl methyl ether using PtO2 as a catalyst. The physical properties of these compounds, such as viscosity, dielectric constant, and ionic conductivity, were characterized. Among them, [3-(2-(2-methoxyethoxy)ethoxy)-propyl]triethoxysilane (TESM2) exhibited a commercial viable ionic conductivity of 1.14 mS cm(-1) and a wide electrochemical window of 5.2 V. A preliminary investigation was conducted by using TESM2 as an electrolyte solvent for high-voltage applications in lithium-ion batteries. Using 1 M LiPF6 in TESM2 with 1 vol% vinyl carbonate as an electrolyte, LiCoO2/Li half-cell delivered a specific capacity of 153.9 mAh g(-1) and 90 % capacity retention after 80 cycles (3.0-4.35 V, 28 mA g(-1)); Li1.2Ni0.2Mn0.6O2/Li4Ti5O12 full cell exhibited the initial capacity of 161.3 mAh g(-1) and 86 % capacity retention after 30 cycles (0.5-3.1 V, 18 mA g(-1)).
文章类型	Article
关键词	Trialkoxysilanes Electrolytes High Voltage Lithium-ion Batteries
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1007/s11581-013-0888-z
研究领域[WOS]	Chemistry ; Electrochemistry ; Physics
关键词[WOS]	CATHODE MATERIALS ; ELECTROCHEMICAL PERFORMANCE ; SULFONE ELECTROLYTES ; CELLS ; CARBONATE ; SPINEL
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter
WOS记录号	WOS:000325634800014
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10106
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Qin, Xueying,Wang, Jinglun,Mai, Yongjin,et al. Oligo(ethylene oxide)-functionalized trialkoxysilanes as novel electrolytes for high-voltage lithium-ion batteries[J]. IONICS,2013,19(11):1567-1572.
APA	Qin, Xueying,Wang, Jinglun,Mai, Yongjin,Tang, Daoping,Zhao, Xinyue,&Zhang, Lingzhi.(2013).Oligo(ethylene oxide)-functionalized trialkoxysilanes as novel electrolytes for high-voltage lithium-ion batteries.IONICS,19(11),1567-1572.
MLA	Qin, Xueying,et al."Oligo(ethylene oxide)-functionalized trialkoxysilanes as novel electrolytes for high-voltage lithium-ion batteries".IONICS 19.11(2013):1567-1572.