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Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media
Chen, Aibing1; Zhao, Guoying1,2; Chen, Jinzhu2; Chen, Limin3; Yu, Yifeng1
2013
Source PublicationRSC ADVANCES
Volume3Issue:13Pages:4171-4175
AbstractA combination of "water soluble'' palladium nanoparticles stabilized by an ionic liquid-like copolymer and phosphotungstic acid synergistically promotes selective hydrogenation of phenol to cyclohexanone. The nanocatalyst preparation and selective phenol hydrogenation are successfully combined into a one-pot process in this research. Conversion exceeding 99% was achieved with >99% selectivity under an atmospheric pressure of hydrogen in aqueous media. Moreover, even at room temperature, >99% conversion and >99% selectivity could still be obtained. The generality of the catalyst system for this reaction was demonstrated by selective hydrogenation of other hydroxylated aromatic compounds with similar performance.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c3ra21663b
WOS Subject ExtendedChemistry
WOS KeywordSUPERCRITICAL CARBON-DIOXIDE ; SUPPORTED PD ; HETEROGENEOUS CATALYSIS ; CYCLOHEXANE OXIDATION ; BENZENE ; PHASE ; METAL ; PRECURSORS ; SILICA ; STATE
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000315818200009
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10102
Collection中国科学院广州能源研究所
Affiliation1.Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Chen, Aibing,Zhao, Guoying,Chen, Jinzhu,et al. Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media[J]. RSC ADVANCES,2013,3(13):4171-4175.
APA Chen, Aibing,Zhao, Guoying,Chen, Jinzhu,Chen, Limin,&Yu, Yifeng.(2013).Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media.RSC ADVANCES,3(13),4171-4175.
MLA Chen, Aibing,et al."Selective hydrogenation of phenol and derivatives over an ionic liquid-like copolymer stabilized palladium catalyst in aqueous media".RSC ADVANCES 3.13(2013):4171-4175.
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