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Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials
Liu, Ruliang1,3; Chen, Jinzhu1; Huang, Xing1; Chen, Limin2; Ma, Longlong1; Li, Xinjun1
2013
Source PublicationGREEN CHEMISTRY
Volume15Issue:10Pages:2895-2903
AbstractA series of sulfonic acid-functionalized carbon materials (C-SO3H), including poly(p-styrenesulfonic acid)-grafted carbon nanotubes (CNT-PSSA), poly(p-styrenesulfonic acid)-grafted carbon nanofibers (CNF-PSSA), benzenesulfonic acid-grafted CMK-5 (CMK-5-BSA), and benzenesulfonic acid-grafted carbon nanotubes (CNT-BSA), have been studied for fructose dehydration to 5-hydroxymethylfurfural (HMF) and fructose alcoholysis to alkyl levulinate. A study for optimizing the reaction conditions such as the catalyst loading, the reaction time, and the temperature has been performed. Under the optimal conditions, high HMF and ethyl levulinate yields of up to 89% and 86%, respectively, are obtained. The catalytic activities of C-SO3H for the conversions of fructose into both HMF and ethyl levulinate follow the order of their acid strength. The relationship between the catalytic activity and acid density of C-SO3H shows a linear correspondence in the fructose dehydration to HMF. The facile separation, ease of recovery, and high thermal stability make the developed C-SO3H efficient and environment-friendly catalytic materials for transforming biomass carbohydrate into fine chemicals.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c3gc41139g
WOS Subject ExtendedChemistry
WOS KeywordETHYL LEVULINATE ; IONIC LIQUIDS ; METHYL LEVULINATE ; FURFURYL ALCOHOL ; MESOPOROUS CARBON ; AMORPHOUS-CARBON ; BIPHASIC SYSTEM ; SULFURIC-ACID ; BIOMASS ; DEHYDRATION
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000325593600034
Citation statistics
Cited Times:105[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10098
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Liu, Ruliang,Chen, Jinzhu,Huang, Xing,et al. Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials[J]. GREEN CHEMISTRY,2013,15(10):2895-2903.
APA Liu, Ruliang,Chen, Jinzhu,Huang, Xing,Chen, Limin,Ma, Longlong,&Li, Xinjun.(2013).Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials.GREEN CHEMISTRY,15(10),2895-2903.
MLA Liu, Ruliang,et al."Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials".GREEN CHEMISTRY 15.10(2013):2895-2903.
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