Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials

doi:10.1039/c3gc41139g

GIEC OpenIR > 中国科学院广州能源研究所

	Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials
	Liu, Ruliang 1,3; Chen, Jinzhu1 ; Huang, Xing 1; Chen, Limin 2; Ma, Longlong1 ; Li, Xinjun1
	2013
发表期刊	GREEN CHEMISTRY
卷号	15 期号:10 页码:2895-2903
摘要	A series of sulfonic acid-functionalized carbon materials (C-SO3H), including poly(p-styrenesulfonic acid)-grafted carbon nanotubes (CNT-PSSA), poly(p-styrenesulfonic acid)-grafted carbon nanofibers (CNF-PSSA), benzenesulfonic acid-grafted CMK-5 (CMK-5-BSA), and benzenesulfonic acid-grafted carbon nanotubes (CNT-BSA), have been studied for fructose dehydration to 5-hydroxymethylfurfural (HMF) and fructose alcoholysis to alkyl levulinate. A study for optimizing the reaction conditions such as the catalyst loading, the reaction time, and the temperature has been performed. Under the optimal conditions, high HMF and ethyl levulinate yields of up to 89% and 86%, respectively, are obtained. The catalytic activities of C-SO3H for the conversions of fructose into both HMF and ethyl levulinate follow the order of their acid strength. The relationship between the catalytic activity and acid density of C-SO3H shows a linear correspondence in the fructose dehydration to HMF. The facile separation, ease of recovery, and high thermal stability make the developed C-SO3H efficient and environment-friendly catalytic materials for transforming biomass carbohydrate into fine chemicals.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c3gc41139g
研究领域[WOS]	Chemistry
关键词[WOS]	ETHYL LEVULINATE ; IONIC LIQUIDS ; METHYL LEVULINATE ; FURFURYL ALCOHOL ; MESOPOROUS CARBON ; AMORPHOUS-CARBON ; BIPHASIC SYSTEM ; SULFURIC-ACID ; BIOMASS ; DEHYDRATION
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000325593600034
引用统计	被引频次：175[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10098
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Liu, Ruliang,Chen, Jinzhu,Huang, Xing,et al. Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials[J]. GREEN CHEMISTRY,2013,15(10):2895-2903.
APA	Liu, Ruliang,Chen, Jinzhu,Huang, Xing,Chen, Limin,Ma, Longlong,&Li, Xinjun.(2013).Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials.GREEN CHEMISTRY,15(10),2895-2903.
MLA	Liu, Ruliang,et al."Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials".GREEN CHEMISTRY 15.10(2013):2895-2903.