High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system

doi:10.1039/c3gc40667a

GIEC OpenIR > 中国科学院广州能源研究所

	High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system
	Shi, Ning 1,2; Liu, Qiying1 ; Zhang, Qi1 ; Wang, Tiejun1 ; Ma, Longlong1
	2013
发表期刊	GREEN CHEMISTRY
卷号	15 期号:7 页码:1967-1974
摘要	A high 5-hydroxymethylfurfural (HMF) yield of 53 mol% was obtained by direct degradation of cellulose in a biphasic system with concentrated NaHSO4 and ZnSO4 as co-catalysts, with 96% of cellulose conversion in 60 min. The high concentration of catalysts in the aqueous solution and the high volume ratio of organic phase to aqueous phase were responsible for the excellent performance. The depolymerization of cellulose is the rate-determine step, and the formed glucose could be efficiently converted by concentrated catalysts in the aqueous solution, leading to low concentration of glucose in the solution and thus suppressing the side reactions such as humin and char formation.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c3gc40667a
研究领域[WOS]	Chemistry
关键词[WOS]	LIGNOCELLULOSIC BIOMASS ; TRANSPORTATION FUELS ; CATALYTIC CONVERSION ; REACTION PATHWAYS ; LEVULINIC ACID ; D-GLUCOSE ; FRUCTOSE ; SALTS ; WATER ; CHEMICALS
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000320781200026
引用统计	被引频次：201[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10077
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Shi, Ning,Liu, Qiying,Zhang, Qi,et al. High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system[J]. GREEN CHEMISTRY,2013,15(7):1967-1974.
APA	Shi, Ning,Liu, Qiying,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2013).High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system.GREEN CHEMISTRY,15(7),1967-1974.
MLA	Shi, Ning,et al."High yield production of 5-hydroxymethylfurfural from cellulose by high concentration of sulfates in biphasic system".GREEN CHEMISTRY 15.7(2013):1967-1974.