Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Production of cyclohexane from lignin degradation compounds over Ni/ZrO2-SiO2 catalysts | |
Zhang, Xinghua1,2; Wang, Tiejun1; Ma, Longlong1; Zhang, Qi1; Huang, Xiaoming1,2; Yu, Yuxiao1,2 | |
2013-12-01 | |
发表期刊 | APPLIED ENERGY |
卷号 | 112页码:533-538 |
摘要 | The main products of lignin degradation are phenolic compounds. It is meaningful to study the processes by which cyclohexane is produced from phenolic compounds via hydrodeoxygenation (HDO), because it could be used as fuel additives, chemical feedstock and solvent. In this work, support material ZrO2-SiO2 mixed oxides with different Si/Zr ratio were synthesized, and a series of Ni/SiO2-ZrO2 catalysts with different Ni loading were prepared by impregnation method. The exploration of HDO process was carried out using phenol and guaiacol as model compounds. Effects of Si/Zr ratio, Ni loading and reaction temperature on conversion of phenol and guaiacol as well as distribution of HDO products were systematically investigated. The results showed that almost all of phenol and guaiacol could be effectively converted into O-free products. And the selectivity of cyclohexane was in excess of 90%. (C) 2013 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Lignin Phenolic Compounds Ni/zro2-sio2 Cyclohexane Hydrodeoxygenation (Hdo) |
WOS标题词 | Science & Technology ; Technology |
DOI | 10.1016/j.apenergy.2013.04.077 |
研究领域[WOS] | Energy & Fuels ; Engineering |
关键词[WOS] | ETHANOL-PRODUCTION ; HYDRODEOXYGENATION ; CONVERSION ; ACID |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS类目 | Energy & Fuels ; Engineering, Chemical |
WOS记录号 | WOS:000329377800056 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10035 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,et al. Production of cyclohexane from lignin degradation compounds over Ni/ZrO2-SiO2 catalysts[J]. APPLIED ENERGY,2013,112:533-538. |
APA | Zhang, Xinghua,Wang, Tiejun,Ma, Longlong,Zhang, Qi,Huang, Xiaoming,&Yu, Yuxiao.(2013).Production of cyclohexane from lignin degradation compounds over Ni/ZrO2-SiO2 catalysts.APPLIED ENERGY,112,533-538. |
MLA | Zhang, Xinghua,et al."Production of cyclohexane from lignin degradation compounds over Ni/ZrO2-SiO2 catalysts".APPLIED ENERGY 112(2013):533-538. |
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